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Napoli made the perfect start as reigning Champions of Italy, conquering newly-promoted Sassuolo with goals from Scott McTominay and debutant Kevin De Bruyne.

The Partenopei began the defence of their title with De Bruyne and Lorenzo Lucca straight into the starting XI, but Romelu Lukaku was ruled out for three to four months. The Neroverdi had Edoardo Iannoni suspended, Ruan Tressoldi, Laurs Skjellerup and Kristian Thorstvedt injured.

See how it all unfolded on the Liveblog.

De Bruyne made an immediate impact, volleying over within 25 seconds, then finding Amir Rrahmani to drill wide after a corner.

It was Scott McTominay who scored the first goal of the 2025-26 season, peeling away from defenders for a glancing free header into the near top corner from eight yards on the Matteo Politano cross.

Josh Doig tested Alex Meret after a surge down the left, but McTominay almost added another on the stroke of half-time, his right-foot curler from the edge of the box smacking against the crossbar.

Domenico Berardi celebrated a new contract this week and nearly marked it with a goal, his ferocious snapshot flashing across the face of goal to skim the far post.

Napoli hit the woodwork for the second time on 55 minutes, this time Politano’s deflected effort off the post from a McTominay assist, with Lucca unable to get on the rebound.

De Bruyne scored a goal on his Serie A debut, even if it was unintentional, because his free kick from the touchline skimmed the heads of both Lucca and McTominay to bounce off the ground and in at the far bottom corner.

Tarek Muharemovic tested an uncertain Alex Meret from distance, but Sassuolo went down to 10 men as Ismael Koné received a second yellow card for his clumsy sliding tackle on Lucca.

Sassuolo 0-2 Napoli

McTominay 17 (N), De Bruyne 57 (N)

Sent off: Koné 79 (S)

23-08-2025 17:30 MatchDay 1 Mapei Stadium - Città del Tricolore

Napoli 0 - 2

Player statistic

1st half
    17' Scott McTominay (Assist: Matteo Politano)
2nd half
    46' Lorenzo Lucca
Domenico Berardi 56'    
    57'

67'     Ismaël Koné

79'    

Match statistic

38 Possession % 62 7 Total shots 13 2 Shots on target 4 4 Shots off target 4 1 Blocked shots 5 1 Corners 2 17 Fouls 17 Sassuolo Napoli

Starting lineups

Stefano Turati Goalkeeper
Josh Doig Defender 81'
Filippo Romagna Defender
Tarik Muharemovic Defender Daniel Boloca Midfielder
Ismaël Koné Midfielder Luca Lipani Midfielder 73'
Andrea Pinamonti Attacker 90'
Armand Lauriente Attacker 81'
Domenico Berardi Attacker 90'
Alex Meret Goalkeeper
Amir Rrahmani Defender
Juan Jesus Defender
Mathías Olivera Defender 89'
Frank Anguissa Midfielder
Kevin De Bruyne Midfielder
Scott McTominay Midfielder 89'
Stanislav Lobotka Midfielder 82' Lorenzo Lucca Attacker 82'
Matteo Politano Attacker

76'

Substitutes

Filippo Missori Defender Cristian Volpato Midfielder
Giacomo Satalino Goalkeeper Gioele Zacchi Goalkeeper Edoardo Pieragnolo Defender Samuele Mulattieri Attacker
Arijanet Muric Goalkeeper Agustín Álvarez Attacker Jay Idzes Defender Alieu Fadera Midfielder 73' Andrea Ghion Defender 81'
Fali Candé Defender 81' Luca Moro Attacker 90' Nicholas Pierini Attacker 90' Nikita Contini Goalkeeper Alessandro Zanoli Defender
Walid Cheddira Attacker Sam Beukema Defender Luca Marianucci Defender Luis Hasa Midfielder
David Neres Attacker 76'
Billy Gilmour Midfielder 82'
Noa Lang Attacker 82'
Leonardo Spinazzola Defender 89'
Antonio Vergara Midfielder

89'

This article first appeared on Football Italia and was syndicated with permission.

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